Synthesis of novel α-functionalized phosphinic acid derivatives of thiophene and the first crystal structure of an α-hydroxyalkylphosphinate

Author(s)
Author(s)
McPartlin, M.
Sanganee, M. J.
Woodroffe, T. M.
Geraldes, C. F. G. C.
Date Issued
1998
Publisher
Royal Society of Chemistry
Journal
Chemical Communications
Issue
19
Start page
2073
End page
2074
Abstract
Reaction of 2,5-diformylthiophene with Ph2CHNH2 and hypophosphorus acid yields novel α-hydroxy- or α-amino-methylphosphinic acid derivatives depending on reaction conditions; the X-ray structure analysis of diphenylmethylammonium 5-formyl-2-thienyl(hydroxy)methylphosphinate provides the first direct structural information on the α-hydroxyalkylphosphinate class of compounds.
URI
DOI
SFU Affiliated Publication
No
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